Trim any fat from pork chops. Combine pork and next 6 ingredients in a zip-top plastic bag. Seal; marinate in refrigerator 8 hours or overnight.
Remove pork from bag, reserving marinade. Prepare grill. Place pork on rack coated with cooking spray; grill pork chops, turning and basting frequently with reserved marinade.
When pork chops are about 8 minutes from being cooked, add pineapple to grill; grill pineapple until lightly browned, turning occasionally.
Serve chops with pineapple.
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